High School

By titration, it is found that 66.9 mL of 0.111 M NaOH(aq) is needed to neutralize 25.0 mL of HCl(aq). Calculate the concentration of the HCl solution.

A) 0.149 M
B) 0.375 M
C) 0.111 M
D) 0.449 M

Answer :

Final answer:

The concentration of the HCl solution is calculated to be 0.297 M. Thus, none of the given options is correct.

Explanation:

Given the titration of 25.0 mL of HCl with 66.9 mL of 0.111 M NaOH, we have the balanced equation:

NaOH(aq) + HCl(aq) → NaCl(aq) + H₂O(l)

The reaction shows that NaOH and HCl react on a 1:1 molar basis.

We can calculate the moles of NaOH used in the titration:

Moles of NaOH = Volume (L) x Molarity (M)

Moles of NaOH = 0.0669 L x 0.111 M

Moles of NaOH = 0.00743.

Since the amount of HCl is equal to the amount of NaOH that reacted, we have 0.00743 moles of HCl.

To find the concentration of HCl, we use the formula:

Concentration of HCl = Moles of HCl / Volume of HCl solution (L)

Concentration of HCl = 0.00743 moles / 0.025 L

Concentration of HCl = 0.2972 M, which rounds off to 0.297 M.

Hence, the concentration of the HCl solution is 0.297 M.

Therefore, none of the given options is correct.