Answer :
Amines have basic properties because of the presence of an unshared pair of electrons on the nitrogen atom.The correct answer is option (d).
Amines are organic compounds that contain a nitrogen atom bonded to one or more carbon atoms. The basic properties of amines are attributed to the presence of an unshared pair of electrons on the nitrogen atom. This unshared pair of electrons is available for bonding with a proton (H+) from an acid, resulting in the formation of a positively charged ammonium ion.When an amine reacts with an acid, such as hydrochloric acid (HCl), the unshared pair of electrons on the nitrogen atom accepts a proton from the acid, forming a positively charged ammonium ion.
This protonation of the amine increases its positive charge and leads to the basic nature of amines. In contrast, options a, b, and c are incorrect because they do not adequately explain the basic properties of amines. A positive charge on the nitrogen atom (option a) is a result of protonation, not the cause of basicity. The ability of the nitrogen atom to give up hydrogen atoms (option b) does not contribute to the basicity of amines. Option c, a sulfhydryl functional group, is unrelated to the basic properties of amines. Hence option (d) is the correct answer.
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