High School

A solution is prepared by dissolving 38.6 g of sucrose (C₁₂H₂₂O₁₁) in 495 g of water. Determine the mole fraction of sucrose if the final volume of the solution is 508 mL. (Density of water is 1.00 g/mL)

Answer :

Mole fraction of sucrose = 0.1128 mol / 27.5718 mol = 0.0041 , the mole fraction of sucrose in the solution is approximately 0.0041.

To calculate the mole fraction of sucrose in the solution, we need to first calculate the number of moles of sucrose and water, and then use these values to determine the mole fraction.

Given:

Mass of sucrose (C₁₂H₂₂O₁₁) = 38.6 g

Mass of water = 495 g

Final volume of the solution = 508 mL

First, let's calculate the number of moles of sucrose (C₁₂H₂₂O₁₁):

Molar mass of sucrose (C₁₂H₂₂O₁₁) = (12 × 12.01 g/mol) + (22 × 1.01 g/mol) + (11 × 16.00 g/mol) = 342.34 g/mol

Number of moles of sucrose = Mass of sucrose / Molar mass of sucrose

Number of moles of sucrose = 38.6 g / 342.34 g/mol

Next, let's calculate the number of moles of water:

Molar mass of water (H₂O) = (2 × 1.01 g/mol) + (16.00 g/mol) = 18.02 g/mol

Number of moles of water = Mass of water / Molar mass of water

Number of moles of water = 495 g / 18.02 g/mol

Now, let's calculate the total moles of solute and solvent in the solution:

Total moles = Moles of sucrose + Moles of water

Next, we need to convert the final volume of the solution to liters:

Final volume of the solution = 508 mL = 508 mL × (1 L / 1000 mL) = 0.508 L

Now, let's calculate the mole fraction of sucrose:

Mole fraction of sucrose = Moles of sucrose / Total moles

Substituting the calculated values, we can now calculate the mole fraction of sucrose in the solution.

Moles of sucrose = 38.6 g / 342.34 g/mol = 0.1128 mol

Moles of water = 495 g / 18.02 g/mol = 27.459 mol

Total moles = 0.1128 mol + 27.459 mol = 27.5718 mol

Mole fraction of sucrose = 0.1128 mol / 27.5718 mol = 0.0041

Therefore, the mole fraction of sucrose in the solution is approximately 0.0041.

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